When talking about graphene, we have to initially mention the all-natural mineral graphite that is commonly present in our life.
As an allotrope of carbon, graphite is a layered product, and the carbon atoms inside graphite are prepared layer by layer. Carbon atoms in the exact same layer “hold hands” and are closely attached, but the mix of carbon atoms in between various layers hangs, like a pile of playing cards. With a gentle push, the cards will slide apart.
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From the perspective of chemical structure, graphite is a transitional crystal in between atomic crystals, metal crystals and molecular crystals. In the crystal, carbon atoms in the exact same layer type covalent bonds with sp2 hybridization, each carbon atom is linked to three various other carbon atoms, and six carbon atoms create a normal hexagonal ring on the same aircraft, stretching to form a sheet framework.
If graphite is a stack of playing cards, after that graphene is just one of the cards in this stack of playing cards. Graphene is a two-dimensional material made up of a single layer of carbon atoms. Stacking graphene layer by layer is graphite. A 1 mm thick graphite consists of about 3 million layers of graphene.
Although graphene exists in nature, it is difficult to peel a single layer structure.
More than 20 years earlier, Andre Geim and Konstantin Novoselov, scientists at the University of Manchester in the UK, thought that there should be a method to obtain a solitary layer of graphite.
How can a single layer of graphite be peeled? Researchers took a really “simple and unrefined” approach – sticking it with tape.
“Similar to when we compose a typo on paper, we will stick the typo with tape.” Based on this, researchers strongly associate that if tape can stay with the surface of paper, can it likewise stay with layers of graphite?
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In the experiment, scientists stuck both sides of pyrolytic graphite flakes to a special tape, and detached the tape, the graphite sheet was split right into 2. Although the thickness of graphite at this time is still much from that of a solitary layer of graphite, scientists have actually confirmed the expediency of this approach – each time the tape is made use of, the graphite ends up being thinner. By insisting on using this “mechanical peeling approach” to repeat the operation, they lastly got a slim sheet consisting of only one layer of carbon atoms, which is graphene.
Nevertheless, this approach of repetitively exfoliating graphite sheets with tape to get graphene has low production efficiency and can just be made use of to prepare micron-thick graphene, and can not be mass-produced industrially.
Later on, with the enhancement of scientific and technological degrees, the prep work method of graphene has actually likewise made great progress. At present, along with this traditional physical and mechanical exfoliation method, there are likewise many techniques for preparing graphene, such as redox method, solvent exfoliation method, chemical vapor deposition, etc
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